Journal of forensic sciences

Measuring the hallucinogenic compounds psilocin and psilocybin in magic mushrooms using advanced chemical analysis

Updated

Abstract

Detection limits for psilocin and psilocybin ranged from 1 to 25 pg using liquid chromatography-mass spectrometry.

  • Liquid chromatography-mass spectrometry provided complete discrimination between psilocin and psilocybin without the need for chemical modification.
  • Tandem mass spectrometry increased specificity and accuracy compared to standard mass spectrometry.
  • Intra- and inter-day variability for the mass spectrometric method was between 4.21% and 5.93%.
  • Analysis of real samples revealed psilocin and psilocybin contents varied widely, from 0.60 to 1.4 mg/g for psilocin and 0.18 to 3.8 mg/g for psilocybin.

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